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　　理學院可見光誘導催化的有機合成方法學報告

　　題目：Visible-Light-Driven Fine Chemical Synthesis Using Inexpensive Natural Gases and Hydrocarbons as Feedstocks in Batch and Flow Reactors

　　報告人：吳杰博士，新加坡國立大學化學系tenure-tracked助理教授，博士生導師

　　時間：2018年12月27日，14點30分

　　地點：理學院報告廳

　　歡迎廣大師生參加!

　　專家介紹：

　　吳杰博士，新加坡國立大學化學系tenure-tracked助理教授，博士生導師。

　　教育工作經歷：

　　?2006年6月，本科畢業于北京師范大學化學系

　　?2012年5月，博士畢業于美國波士頓大學，師從James S. Panek教授從事天然產物全合成研究，期間加入波士頓大學化學方法和分子庫研究中心，在John A. Porco教授的指導下完成多樣導向合成的課題

　　?2012年7月-2015年1月，美國麻省理工學院(MIT)化學系和化工系聯合培養的博士后，師從Timothy F. Jamison教授和T. Alan Hatton教授從事連續流動合成的研究;

　　?2015年5月-至今，新加坡國立大學化學系，tenure-tracked的助理教授，博士生導師。

　　研究領域：

　　課題組集中于發展新的可見光誘導的催化方法學，以天然氣體或者便宜易得的C-H和Si-H鍵化合物作為原料，合成具有高附加值的化學品;并同時利用微型流體管路反應器和開發新的反應器模式增強光照反應的效率，實現傳統化學條件下難以達到的反應環境。在迄今三年時間內，并先后在J. Am. Chem. Soc.、Angew Chem. Int. Ed.、Chem、ACS Catal.、Chem. Sci.等雜志上發表論文19篇，申請專利2項，其中多篇文章被Angew Chem. Int. Ed.，Synfacts，X-MOL，WeeChem等所評述。

　　個人榮譽：

　　?03/2017, the 4th Green & Sustainable Manufacturing Award from GSK-EDB

　　?11/2017, Asian Core Program Lectureship Award from China in the 12th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-12).

　　?09/2018, the Department Young Chemist Award 2018 from Department of Chemistry, National University of Singapore.

　　?11/2018, Asian Core Program Lectureship Award from Taiwan and Thailand in the 13th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-13)

　　?11/2018, Thieme Chemistry Journal Award (2019)

　　發表文章的代表作：

　　1.Xue, F.?; Deng, H.?; Xue, C.; Mohamed, D. K. B.; Tang, K. Y.; Wu, J.* “Reaction Discovery Using Acetylene Gas as the Chemical Feedstock Accelerated by the ‘Stop-Flow’ Micro-Tubing Reactor System” Chem. Sci. 2017, 8, 3623-3627. (?Co-first authors)

　　2. Zhou, R.; Liu, H.; Tao, H.; Yu, X.; Wu, J.* Metal-free direct alkylation of unfunctionalized allylic/benzylic sp3 C–H bonds via photoredox induced radical cation deprotonation. Chem. Sci. 2017, 8, 4654-4659.This article was featured in Synfacts.

　　3. Deng, H.; Fan, X.; Chen, Z.; Xu, Q.; & Wu, J.* Photo-induced nickel-catalyzed chemo- and regioselective hydroalkylation of internal alkynes with ether and amide a-hetero C(sp3)-H bonds J. Am. Chem. Soc. 2017, 139, 13579-13584.This work was highlighted by NUS FoS,Phys.org and X-MOL.

　　4. Zhou, R.; Goh, Y. Y.; Liu, H.; Tao, H.; Li, L.; Wu, J.* “Visible-Light-Mediated Metal-Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si-H Activation” Angew. Chem. Int. Ed. 2017, 56, 16621-16625.This article was featured in Synfacts and X-MOL.

　　5. Hou, J., Ee, A., Feng, W., Xu, J.-H., Zhao, Y.,* Wu, J.* Visible-Light-Driven Alkyne Hydro-/Carbocarboxylation Using CO2 via Iridium/Cobalt Dual Catalysis for Divergent Heterocycle Synthesis J. Am. Chem. Soc.2018, 140, 5257-5263. This work was highlighted by X-MOL.

　　6. Fan, X.-Z., Rong, J.-W., Wu, H.-L., Zhou, Q., Deng, H.-P., Tan, J. D., Xue, C.-W., Wu, L.-Z., Tao, H.-R., Wu, J.* Eosin Y as a Direct Hydrogen Atom Transfer Photocatalyst for the Functionalization of C-H Bonds Angew. Chem. Int. Ed. 2018, 57, 8514-8518. This paper has been selected as Hot Topic in Organocatalysis and Photocatalysis.This work was highlighted by Angew. Chem. Int. Ed. (Prof. Chen Jiarong and Prof. Xiao Wenjing) and X-MOL.

　　7. Liu, H., Ma, L., Zhou, R., Chen, X.,* Fang, W., Wu, J.* One-Pot Photo-Mediated Giese Reaction/Friedel-Crafts Hydroxyalkylation/Oxidative Aromatization to Access Naphthalene Derivatives from Toluenes and Enones ACS Catal. 2018, 8, 6224-6229. This paper was highlighted by X-MOL.

　　8. Deng, H.-P., Zhou, Q., Wu, J.* Micro-Tubing Reactor-Assisted Aliphatic C-H Functionalization Utilizing HCl as the Hydrogen Atom Transfer Catalyst Precursor in Conjunction with an OrganoPhotoredox Catalyst Angew. Chem. Int. Ed.2018, 57,12661-12665. This paper was highlighted by X-MOL.

　　9. Li, J., Luo Y., Cheo, H. W., Lan, Y.,* Wu, J.* Photoredox Catalysis Modulated Nickel-Catalyzed Divergent Difunctionalization of Ethylene Chem2018, DOI: 10.1016/j.chempr.2018.10.006.

　　10. Hou, J., Ee, A., Cao, H., Ong, H.-W., Xu, J.-H. Wu, J.* Visible‐Light‐Mediated Metal‐Free Difunctionalization of Alkenes with CO2 and Silanes or C(sp3)-H Alkanes Angew. Chem. Int. Ed. 2018, 57, 17220-17224.This paper has been selected as Hot Paper by Angew. Chem. Int. Ed (Topics: C-H Activation, Carbon Dioxide, and Photocatalysis).This paper was highlighted by X-MOL and WeeChem.

　　11. Cao, H., Jiang, H., Feng, H., Kwan, J. M. C., Liu, X., Wu, J.* Photo-Induced Decarboxylative Heck-Type Coupling of Unactivated Aliphatic Acids and Terminal Alkenes in the Absence of Sacrificial Hydrogen Acceptors J. Am. Chem. Soc.2018, 140, 16360-16367.

　　12. Ng, C. K., Toh, R. W., Lin, T. T., Luo, H.-K., Hor, T. S. A.,* Wu, J.* Metal-salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO2 with epoxides at ambient conditions Chem. Sci.2019, DOI: 10.1039/C8RE00216A.

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